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University of California at Irvine   Department of Chemistry   
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Cover image for the 2012 paper on reactive nano-DESI
Paper 83

Secondary Brown Carbon From Reactions of Ammonia and Amines

This collection of articles focuses on reactions of ammonia and amines with carbonyl compounds resulting in formation of nitrogen-containing compounds, including light-absorbing compounds. The can be regarded as "secondary brown carbon" since they are not directly emitted but rather produced in the atmosphere by various multi-phase processes.

187. Alexandra L. Klodt, Paige K. Aiona, Amanda C. MacMillan, Hyun Ji (Julie) Lee, Xiaolu Zhang, Taylor Helgestad, Gordon A. Novak, Peng Lin, Julia Laskin, Alexander Laskin, Timothy H. Bertram, Christopher D. Cappa, and Sergey A. Nizkorodov
Effect of relative humidity, NOx, and ammonia on physical properties of naphthalene secondary organic aerosol
Environmental Science: Atmospheres, 3 (2023) 991-1007. DOI:10.1039/d3ea00033h  PDF  SI

172. Shupeng Zhu, Kai Wu, Sergey A. Nizkorodov, and Donald Dabdub
Modeling reactive ammonia uptake by secondary organic aerosol in a changing climate: a WRF-CMAQ evaluation
Frontiers in Environmental Science, 10 (2022) 867908. DOI:10.3389/fenvs.2022.867908  PDF  SI

170. Natalie R. Smith, Julia Montoya-Aguilera, Donald Dabdub, and Sergey A. Nizkorodov
Effect of humidity on the reactive uptake of ammonia and dimethylamine by nitrogen-containing secondary organic aerosol
Atmosphere, 12 (2021) 1502. DOI:10.3390/atmos12111502   PDF   SI

159. Matthieu Riva, Jianfeng Sun, V. Faye McNeill, Charline Ragon, Sebastien Perrier, Yinon Rudich, Sergey A. Nizkorodov, Jianmin Chen, Frederic Caupin, Thorsten Hoffmann and Christian George
High pressure inside nanometer-sized particles influences the rate and products of chemical reactions
Environmental Science & Technology, 55 (2021) 7786-7793. DOI:10.1021/acs.est.0c07386  PDF  SI

143. Zhijian Li, Sergey A. Nizkorodov, Hong Chen, Xiaohui Lu, Xin Yang and Jianmin Chen
Nitrogen-containing secondary organic aerosols formation by acrolein reaction with ammonia/ammonium
Atmospheric Chemistry and Physics, 19 (2019) 1343-1356. DOI:10.5194/acp-19-1343-2019  PDF  SI

142. Dagny A. Ullmann, Mallory L. Hinks, Adrian Maclean, Christopher Butenhoff, James Grayson, Kelley Barsanti, Jose L. Jimenez, Sergey A. Nizkorodov, Saeid Kamal, and Allan K. Bertram
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes-Einstein equation
Atmospheric Chemistry and Physics, 19 (2019) 1491-1503. DOI:10.5194/acp-19-1491-2019  PDF  SI

136. Julia Montoya-Aguilera, Mallory L. Hinks, Paige K. Aiona, Lisa M. Wingen, Jeremy R. Horne, Shupeng Zhu, Donald Dabdub, Alexander Laskin, Julia Laskin, Peng Lin and Sergey A. Nizkorodov
Reactive uptake of ammonia by biogenic and anthropogenic organic aerosols
ACS Symposium Series volume 1299, Chapter 7, pp 127-147 in "Multiphase Environmental Chemistry in the Atmosphere", Hunt S., Laskin A., Nizkorodov S.A. Eds., 2018; ISBN13: 9780841233638. DOI:10.1021/bk-2018-1299.ch007  PDF

129. Shupeng Zhu, Jeremy R. Horne, Julia Montoya-Aguilera, Mallory L. Hinks, Sergey A. Nizkorodov, and Donald Dabdub
Modeling reactive ammonia uptake by secondary organic aerosol in CMAQ: application to the continental US
Atmospheric Chemistry and Physics, 18 (2018) 3641-3657. DOI:10.5194/acp-18-3641-2018  PDF SI

128. Jeremy R. Horne, Shupeng Zhu, Julia Montoya-Aguilera, Mallory L. Hinks, Lisa M. Wingen, Sergey A. Nizkorodov, and Donald Dabdub
Reactive uptake of ammonia by secondary organic aerosols: Implications for air quality
Atmospheric Environment, 189 (2018) 1-8. DOI:10.1016/j.atmosenv.2018.06.021  PDF  SI

126. Paige K. Aiona, Hyun Ji (Julie) Lee, Renee Leslie, Peng Lin, Alexander Laskin, Julia Laskin, and Sergey A. Nizkorodov
Photochemistry of products of the aqueous reaction of methylglyoxal with ammonium sulfate
ACS Earth and Space Chemistry 1 (2017) 522-532. DOI:10.1021/acsearthspacechem.7b00075  PDF  SI

124. Paige K. Aiona, Hyun Ji (Julie) Lee, Peng Lin, Forrest Heller, Alexander Laskin, Julia Laskin and Sergey A. Nizkorodov
A role for 2-methyl pyrrole in the browning of 4-oxopentanal and limonene secondary organic aerosol
Environmental Science & Technology, 51 (2017) 11048-11056. DOI:10.1021/acs.est.7b02293  PDF

109. Peng Lin, Sergey A. Nizkorodov, Julia Laskin and Alexander Laskin
Revealing brown carbon chromophores produced in reactions of methylglyoxal with ammonium sulfate
Environmental Science & Technology, 49 (2015) 14257-14266. DOI:10.1021/acs.est.5b03608  PDF  SI

101. Alexander Laskin, Julia Laskin and Sergey A. Nizkorodov
Chemistry of atmospheric brown carbon
(a.k.a. Brown Carbon 101)
Chemical Reviews, 115 (2015) 4335-4382. DOI:10.1021/cr5006167  PDF

99. Julia Laskin, Alexander Laskin, Sergey A. Nizkorodov, Patrick Roach, Peter Eckert, Mary K. Gilles, Bingbing Wang, Hyun Ji (Julie) Lee, Qichi Hu
Molecular selectivity of brown carbon chromophores
Environmental Science & Technology, 48 (2014) 12047-12055. DOI:10.1021/es503432r  PDF  SI

95. Jorge Michel Flores, Rebecca A. Washenfelder, Gabriela Adler, Hyun Ji (Julie) Lee, Lior Segev, Julia Laskin, Alexander Laskin, Sergey A. Nizkorodov, Steven S. Brown and Yinon Rudich
Complex refractive indices in the near-ultraviolet spectral region of biogenic secondary organic aerosol aged with ammonia
Physical Chemistry Chemical Physics, 16 (2014) 10629-10642. DOI:10.1039/C4CP01009D  PDF

93. Hyun Ji (Julie) Lee, Paige K. Aiona, Alexander Laskin, Julia Laskin and Sergey A. Nizkorodov
Effect of solar radiation on the optical properties and molecular composition of laboratory proxies of atmospheric brown carbon
Environmental Science & Technology, 48 (2014) 10217-10226. DOI:10.1021/es502515r  PDF  SI

89. Tran B. Nguyen, Alexander Laskin, Julia Laskin and Sergey A. Nizkorodov
Brown carbon formation from ketoaldehydes of biogenic monoterpenes
Faraday Discussions 165 (2013) 473-494. DOI:10.1039/C3FD00036B PDF SI

87. Hyun Ji (Julie) Lee, Alexander Laskin, Julia Laskin and Sergey A. Nizkorodov
Excitation-emission spectra and fluorescence quantum yields for fresh and aged biogenic secondary organic aerosols
Environmental Science & Technology, 47 (2013) 5763–5770. DOI:10.1021/es400644c PDF SI

83. Julia Laskin, Peter A. Eckert, Patrick J. Roach, Brandi S. Heath, Sergey A. Nizkorodov and Alexander Laskin
Chemical analysis of complex organic mixtures using reactive nanospray desorption electrospray ionization mass spectrometry
Analytical Chemistry, 84 (2012) 7179-7187. DOI:10.1021/ac301533z PDF SI Highlight for this article

77. Katelyn M. Updyke, Tran B. Nguyen and Sergey A. Nizkorodov
Formation of brown carbon via reactions of ammonia with secondary organic aerosols from biogenic and anthropogenic precursors
Atmos. Env. 63 (2012) 22-31. DOI:10.1016/j.atmosenv.2012.09.012 PDF SI

72. Tran B. Nguyen, Paula B. Lee, Katelyn M. Updyke, David L. Bones, Julia Laskin, Alexander Laskin and Sergey A. Nizkorodov
Formation of nitrogen- and sulfur-containing light-absorbing compounds accelerated by evaporation of water from secondary organic aerosols
Journal of Geophysical Research: Atmospheres, 117 (2012) D01207. DOI:10.1029/2011JD016944 PDF SI

66. Julia Laskin, Alexander Laskin, Patrick J. Roach, Gordon W. Slysz, Gordon A. Anderson, Sergey A. Nizkorodov, David L. Bones and Lucas Q. Nguyen
High-resolution desorption electrospray ionization mass spectrometry for chemical characterization of organic aerosols
Analytical Chemistry, 82 (2010) 2048-2058. DOI:10.1021/ac902801f  PDF

62. David L. Bones, Dana K. Henricksen, Stephen A. Mang, Michael Gonsior, Adam P. Bateman, Tran B. Nguyen, William J. Cooper and Sergey A. Nizkorodov
Appearance of strong absorbers and fluorophores in limonene-O3 secondary organic aerosol due to NH4+-mediated chemical aging over long time scales
Journal of Geophysical Research: Atmospheres, 115 (2010) D05203.  DOI:10.1029/2009JD012864  PDF  SI

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